Roy A. Periana

University of Florida — United States

Materials Science · Physical Sciences

50h-index11.1kcitations175works0.72yr avg
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Research Topics

Crystallization and Solubility Studies(47), X-ray Diffraction in Crystallography(47), Asymmetric Hydrogenation and Catalysis(45), Catalytic C–H Functionalization Methods(43), Catalysis and Oxidation Reactions(41)

Publications175 total

Reactivity, selectivity, and mechanism of Bi(V) promoted methane C-H functionalization in concentrated sulfuric acid
Journal of Organometallic Chemistry·2026
Computational and experimental evidence for Sb(<scp>v</scp>) metal mediated C–H activation and oxidative functionalization of arenes
Chemical Science·2025· 2 citedOpen Access
Mechanism and Selectivity of Bi(V)-Aryl Oxyfunctionalization in Trifluoroacetic Acid Solvents
Organometallics·2024
Oxidation of alkanes to alcohols
OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information)·2023Open Access
Reactivity and Mechanisms of Methane, Ethane, and Benzene C–H Amination with an Iodine(III) Bistriflimide Complex
Organometallics·2023· 6 citedOpen Access
Conversion of alkanes to organoseleniums and organotelluriums
OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information)·2023Open Access
Process for the functionalization of heteroalkanes and arenes
OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information)·2023Open Access
Experimental Demonstration and Density Functional Theory Mechanistic Analysis of Arene C–H Bond Oxidation and Product Protection by Osmium Tetroxide in a Strongly Basic/Nucleophilic Solvent
The Journal of Organic Chemistry·2022· 2 cited
Theory and Experiment Demonstrate that Sb(V)-Promoted Methane C–H Activation and Functionalization Outcompete Superacid Protonolysis in Sulfuric Acid
Journal of the American Chemical Society·2021· 20 citedOpen Access
Homogeneous Methane Functionalization
2020· 1 cited
S<sub>N</sub>2 and E2 Branching of Main-Group-Metal Alkyl Intermediates in Alkane CH Oxidation: Mechanistic Investigation Using Isotopically Labeled Main-Group-Metal Alkyls
Organometallics·2020· 6 cited
Selective N Functionalization of Methane and Ethane to Aminated Derivatives by Main-Group-Directed C–H Activation
Organometallics·2019· 15 cited
Selective C−H Functionalization of Methane and Ethane by a Molecular Sb<sup>V</sup> Complex
Angewandte Chemie·2019· 4 citedOpen Access
Supermetal: SbF<sub>5</sub>-mediated methane oxidation occurs by C–H activation and isobutane oxidation occurs by hydride transfer
Dalton Transactions·2019· 13 citedOpen Access
CCDC 1810843: Experimental Crystal Structure Determination
The Cambridge Structural Database·2019Open Access
CCDC 1810844: Experimental Crystal Structure Determination
The Cambridge Structural Database·2019Open Access
Selective C−H Functionalization of Methane and Ethane by a Molecular Sb<sup>V</sup> Complex
Angewandte Chemie International Edition·2018· 29 citedOpen Access
Electrophilic Impact of High-Oxidation State Main-Group Metal and Ligands on Alkane C–H Activation and Functionalization Reactions
Organometallics·2018· 7 citedOpen Access
Mechanisms and Reactivity of Tl(III) Main-Group-Metal–Alkyl Functionalization in Water
Organometallics·2018· 3 citedOpen Access
CCDC 1821480: Experimental Crystal Structure Determination
The Cambridge Structural Database·2018Open Access
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Frequent Co-authors

William A. Goddard(25), Jonas Oxgaard(16), K.J.H. Young(9), Brian G. Hashiguchi(8), Gaurav Bhalla(8), Robert J. Nielsen(7), Daniel H. Ess(7), Douglas J. Taube(6), Steven M. Bischof(6), O. A. Mironov(6), William J. Tenn(6), Vadim R. Ziatdinov(6), Michael M. Konnick(5), Robert G. Bergman(5), C. Bigler Jones(4), Jason M. Gonzales(4), Niles Gunsalus(3), Doug Taube(3), Takaya Matsumoto(3), Hajime Yoshida(3)