Robert D. Bach

University of Delaware — United States

Chemistry · Physical Sciences

48h-index6.8kcitations270works4.02yr avg
OpenAlex↗ORCID↗Google Scholar↗Lab page↗

Accepting Students?

No reports yet. Know if this professor is taking students?

Research Topics

Organic Chemistry Cycloaddition Reactions(48), Chemical Reaction Mechanisms(43), Asymmetric Synthesis and Catalysis(39), Oxidative Organic Chemistry Reactions(37), Inorganic and Organometallic Chemistry(35)

Publications270 total

Mechanism of the Sharpless Epoxidation Reaction: A DFT Study
The Journal of Physical Chemistry A·2024· 4 cited
Correction to “The Bond Dissociation Energy of the N–O Bond”
The Journal of Physical Chemistry A·2022· 1 cited
Mechanism of Orbital Interactions in the Sharpless Epoxidation with Ti(IV) Peroxides: A DFT Study
The Journal of Physical Chemistry A·2021· 7 cited
The Bond Dissociation Energy of the N–O Bond
The Journal of Physical Chemistry A·2021· 62 cited
Bond Dissociation Energy of Peroxides Revisited
The Journal of Physical Chemistry A·2020· 80 cited
Structure and Mechanism for Alkane Oxidation and Alkene Epoxidation with Hydroperoxides, α-Hydroxy Hydroperoxides, and Peroxyacids: A Theoretical Study
The Journal of Physical Chemistry A·2019· 10 cited
The DMDO Hydroxylation of Hydrocarbons via the Oxygen Rebound Mechanism
The Journal of Physical Chemistry A·2016· 17 cited
Mechanism of <i>N</i>-Hydroxylation Catalyzed by Flavin-Dependent Monooxygenases
The Journal of Organic Chemistry·2015· 40 cited
Mechanistic Aspects Regarding the Elimination of H<sub>2</sub>O<sub>2</sub> from C(4a)-Hydroperoxyflavin. The Role of a Proton Shuttle Required for H<sub>2</sub>O<sub>2</sub> Elimination
The Journal of Organic Chemistry·2013· 17 cited
The Role of Acid Catalysis in the Baeyer–Villiger Reaction. A Theoretical Study
The Journal of Organic Chemistry·2012· 30 cited
Role of the Somersault Rearrangement in the Oxidation Step for Flavin Monooxygenases (FMO). A Comparison between FMO and Conventional Xenobiotic Oxidation with Hydroperoxides
The Journal of Physical Chemistry A·2011· 20 cited
The Rate-Limiting Step in P450 Hydroxylation of Hydrocarbons A Direct Comparison of the “Somersault” versus the “Consensus” Mechanism Involving Compound I
The Journal of Physical Chemistry A·2010· 19 cited
Transient Inverted Metastable Iron Hydroperoxides in Fenton Chemistry. A Nonenzymatic Model for Cytochrome P450 Hydroxylation
The Journal of Organic Chemistry·2010· 20 cited
General and Theoretical Aspects of the Peroxide Group
Patai's Chemistry of Functional Groups·2009· 3 cited
Ring Strain Energy in the Cyclooctyl System. The Effect of Strain Energy on [3 + 2] Cycloaddition Reactions with Azides
Journal of the American Chemical Society·2009· 117 cited
The Curtius Rearrangement of Cyclopropyl and Cyclopropenoyl Azides. A Combined Theoretical and Experimental Mechanistic Study
The Journal of Organic Chemistry·2008· 32 citedOpen Access
Mechanism of Thiolate−Disulfide Interchange Reactions in Biochemistry
The Journal of Organic Chemistry·2007· 146 cited
Mechanism of S<sub>N</sub>2 Disulfide Bond Cleavage by Phosphorus Nucleophiles. Implications for Biochemical Disulfide Reducing Agents
The Journal of Organic Chemistry·2007· 94 citedOpen Access
General and Theoretical Aspects of the Peroxide Group
ChemInform·2006· 4 cited
General and Theoretical Aspects of the Peroxide Group
2006· 10 cited
page 1 of 14Next →

Frequent Co-authors

H. Bernhard Schlegel(13), Olga Dmitrenko(10), Mikhail N. Glukhovtsev(10), Joseph J. W. McDouall(5), Carlo Canepa(5), Gregory J. Wolber(5), José L. Andrés(3), Amy L. Owensby(3), Christopher Nagel(3), Carlos González(3), Colin Thorpe(2), Addy Pross(2), Leo Radom(2), Carlos M. Estévez(2), Ming Der Su(2), Julia Winter(2), Joseph M. Fox(2), Lian‐an Liao(2), William Robert Moore(2), Russell C. Klix(2)